|Previous Affiliation||Aizen's Army|
|Previous Occupation||Replacement Sexta Espada|
|Base of Operations||Las Noches|
Battle with the Shinigami GuardEdit
After replacing Grimmjow Jaegerjaquez as the Sexta (Sixth) Espada, Luppi, on Aizen's orders, attacks Karakura Town with several other Arrancar. Upon releasing his Resurreccion, he gains the upper hand against the Shinigami he is battling and becomes interested in fighting Ben Tennyson, but the latter ends up fighting Yammy Llargo instead. Luppi is ultimately defeated by 10th Division Captain Toshiro Hitsugaya when the latter uses his Bankai to trap the arrogant Arrancar in a massive block of ice. However, Luppi is saved by a Negacion, and is taken back to Las Noches.
Following his return to Las Noches, Luppi is quickly killed by Grimmjow when the latter's arm is restored by Orihime in order for the brutal Arrancar to regain his rank.